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We review the interpretation of multiple-scattering theory in terms of muffin-tin orbitals. The use of slightly overlapping muffin-tin wells is justified rigorously. It is shown that the structure constants may be screened for a useful range of positive and negative energies, and that the screening may be chosen to yield desirable properties of the KKR matrix. Energy linearization and the linear muffin-tin-orbital method are discussed.
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